Appendix, Appendix 7.1 ph as a function of mv – KROHNE OPTISENS PH 8590 User Manual

Page 44

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7

APPENDIX

44

OPTISENS PH 8590

www.krohne.com

03/2012 - 4001931401 MA OPTISENS PH 8590 R01 en

Appendix

7.1 pH as a function of mV

The pH-value is the negative decadative logarithm of the hydrogen ion concentration, and it is
directly related to the proportion of hydrogen ions H

+

to hydroxide ions OH

-

in the media. The pH-

electrode measures excess or deficit of the hydrogen ions and gives a proportional millivolt
signal as output. The signal is 59.16 mV per 1 pH at 25°C / 77°F. In clean water there is a total
balance between hydrogen ions and hydroxide ions, the output from the electrode is 0.0 mV and
pH is 7. The millivolt signal is measured by the pH sensor and the corresponding pH value is
calculated in the signal converter.

mV

pH

H

+

ions [mol/l]

OH

-

ions [mol/l]

Example

414

0

1

0.00000000000001

355

1

0.1

0.0000000000001

296

2

0.01

0.000000000001 Coca Cola

237

3

0.001

0.00000000001

177

4

0.0001

0.0000000001 Orange juice

118

5

0.00001

0.000000001

59

6

0.000001

0.00000001 Milk

0

7

0.0000001

0.0000001 Clean water

-59

8

0.00000001

0.000001 Blood

-118

9

0.000000001

0.00001

-177

10

0.0000000001

0.0001

-237

11

0.00000000001

0.001

-296

12

0.000000000001

0.01

-355

13

0.0000000000001

0.1

-414

14

0.00000000000001

1 Sulfa

.book Page 44 Monday, March 19, 2012 2:01 PM

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